Organic Reactions (Volume 71)

Description

For all volumes: the volumes of Organic Reactions are collections of chapters each devoted to a single reaction or a definitive phase of a reaction, of wide applicability. The authors have had experience with the processes surveyed. The subjects are presented from the preparative viewpoint and particular attention is given to limitations, interfering influences, effects of structure and the selection of experimental techniques. Each chapter includes several detailed procedures illustrating the significant modifications of the method. Each chapter contains tablets that include all the examples of the reaction under consideration that the author has been able to find. This volume in the prestigious series includes complete coverage of the catalytic asymmetric Strecker reaction and the preparation of phenols and quinones via Fischer carbene complexes.
Volume 71 contains one chapter: IONIC AND ORGANOMETALLIC-CATALYZED ORGANOSILANE REDUCTIONS
The purpose of this chapter is to present a critical review of synthetically useful variations of ionic methods for hydrogenation of organic compounds. In
practice, ionic hydrogenation involves the formal introduction of hydride from a donor source to an electron-deficient carbon center. The electrophilic centers
can be formed by the departure of a leaving group (nucleofuge) from a saturated center or by the addition of an electrophile to a multiple bond. In the former
mechanism, substitution of hydrogen for the leaving group is the net chemical consequence.
pass: tForgarev71.rar

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1. Ebooks list page : 3042
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3. Electron-Transfer and Electrochemical Reactions; Photochemical and Other Energized Reactions, Volume 15
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5. Mechanisms in Organic Reactions
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7. Catalysis of Organic Reactions
8. Organic Chemistry Reactions
9. Organic Chemistry Reactions
10. Organic Syntheses Based on Name Reactions,2 Ed
11. The Investigation of Organic Reactions and Their Mechanisms
12. The Investigation of Organic Reactions and Their Mechanisms
13. Comprehensive Organic Reactions in Aqueous Media
14. Iron Catalysis in Organic Chemistry: Reactions and Applications
15. Comprehensive Organic Reactions In Aqueous Media (2007)
16. Advanced Free Radical Reactions for Organic Synthesis